Type 321 is a standard austenitic 18/8 chromium nickel alloy with the addition of Titanium making it an excellent choice in elevated temperature environments.
Used in particular applications within 450-850 degrees centigrade, 321 combines high strength with resistance to scaling and phase stability, Some typical areas of application are, furnace components, superheater and afterburner parts, compensators and expansion bellows.
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Stainless steel 321 is a 18Cr-9Ni austenitic stainless steel stabilised with some titanium additions.
This kind of steel is one of the basic grades of the stainless steels range. Titanium bearing (carbide forming element) avoids intergranular corrosion, even on welded pieces without ulterior water quenching.
Alloys stainless steel 321 exhibit austenitic microstructures free of deleterious carbide precipitations but with CNTi precipitations at the grain boundaries. The grade contains some residual ferrite (≈4%) after solution annealing (1000-1100°C - 1832-2012°F) and water quenching.
The main properties are:
- Basic corrosion resistance
- Resistance against intergranular corrosion
- Heat resistant alloy (medium temperature)
- High ductility
Standards
| EURONORM | 1.4541 X6CrNiTi 18-10 |
|---|---|
| AFNOR | Z6 CNT 18-10 |
| DIN | W1.4541 |
| ASTM | A 240 - TP 321 UNS S32100 |
Chemical Analysis
| Typical values (weight %) | |||||
|---|---|---|---|---|---|
| C | Cr | NI | Mo | N | Others |
| 0.050 | 17.5 | 9.2 | - | - | =5x%C ; up to 0.70 |
| PREN (=%Cr+3.3%Mo+16%N) ≥ 18 | |||||
Mechanical Properties
| Tensile properties after water quenching | ||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| °C | °F | Minimum guaranteed values * | Typical values | El % | ||||||||||
| Y.S. 0.2% | Y.S. 1% | UTS | Y.S. 0.2% | Y.S. 1% | UTS | |||||||||
| MPa | Ksi | MPa | Ksi | MPa | Ksi | MPa | Ksi | MPa | Ksi | MPa | Ksi | |||
| 20 | 68 | 200 | 29 | 240 | 35 | 500/ 700 |
73/ 102 |
280 | 40 | 310 | 45 | 600 | 89 | 45 |
| 100 | 212 | 176 | 25 | 208 | 30 | 460 | 67 | 238 | 34 | 260 | 38 | 550 | 82 | 40 |
| 200 | 392 | 157 | 23 | 186 | 27 | 410 | 60 | 200 | 29 | 230 | 33 | 450 | 66 | 35 |
| 300 | 572 | 136 | 20 | 167 | 24 | 390 | 57 | 168 | 26 | 210 | 30 | 435 | 64 | 35 |
| 400 | 752 | 125 | 18 | 156 | 23 | 390 | 57 | 175 | 25 | 200 | 29 | 420 | 61 | 30 |
| 500 | 932 | 119 | 17 | 149 | 22 | 310 | 45 | 168 | 24 | 195 | 28 | 340 | 50 | 30 |
* Following EN 10088 hot rolled plates.
The EN guaranteed values are valid for a thickness from 5-75mm.
| Impact values | |||
|---|---|---|---|
| °C | -269 | -196 | +20 |
| °F | -452 | -320 | 68 |
| KCV (J*cm²) Minimum | 62 | 100 | 150 |
| KCV (J*cm²) Typical | 138 | 160 | 25 |
Physical Properties
| Interval temper °C |
Thermal expansion αx10-6K-1 |
°C | °F | Resistivity (µΩ cm) |
Thermal conductivity (W.m-1.K-1) |
Specific heat (J.kg-1.K-1) |
Young modulus E (GPa) |
Shear modulus G (GPa) |
|---|---|---|---|---|---|---|---|---|
| 20-100 | 16 | 20 | 68 | 73 | 15 | 500 | 200 | 77 |
| 20-200 | 16.5 | 100 | 212 | 77 | 16 | 500 | 194 | 75 |
| 20-300 | 17 | 200 | 392 | 84 | 17.5 | 520 | 186 | 71 |
| 20-400 | 17.5 | 300 | 572 | 91 | 19 | 530 | 179 | 68 |
| 20-500 | 18 | 400 | 752 | 97 | 20.5 | 540 | 172 | 65 |
| 500 | 932 | 102 | 22 | 540 | 165 | 62 | ||
Corrosion Resistance
| Quality corrosion tests guaranteed (special request may be discussed) | |||
|---|---|---|---|
| TEST | Other name | Corrosion (1) | Results |
| ASTM A 262 A | Intergranular | Step or dual structure | |
| ASTM A 262 B | STREICHER | Intergranular | Not recommended |
| ASTM A 262 C | HUEY | Intergranular | Not recommended |
| ASTM A 262 E DIN 50914 RCCM |
STRAUSS | Intergranular | No cracking after bending |
| ASTM G48 A | Pitting | Not recommended (typical CPT = 5°C-41°F) |
|
| ASTM G48 B | ASTM G78 | Crevice | Not recommended (typical CCT ≤ 0°C-32°F) |
(1) kind of corrosion mechanism investigated
Applications
Stainless steel 321 is corrosion resistant in:
- Urban media
- Most of diluted organic acids at moderate temperatures
- Most of food and pharmaceutical products
- Pure phosphoricM
- Whatever concentration in cold solution
- Up to 10% diluted hot solution
- Caustic solutions free of chlorides or fluorides at medium temperatures
The alloys is not corrosion resistant in chloride containing solutions, even diluted, and in sulphuric acid media.
So, the main applications are:
- Food processing and storage
- Chemical industry
- High temperature




